Hacker Newsnew | past | comments | ask | show | jobs | submitlogin

The reaction should be conducted in an oxygen-free, pure nitrogen atmosphere where those compounds should be safe to handle.


When it’s boiled to dryness, crown ether can produce peroxides that are unstable enough to explode on their own with shock or additional heat - no oxygen needed.

It’s a not-uncommon mistake to make in a synthetic lab.


My understanding is that evaporating solvent away doesn't form peroxides. Rather, as an ether ages, it can peroxidize. Removing the solvent concentrates the peroxides is all. Sure, it's a little tricky, but they're reporting results of chemistry research, which doesn't mean immediate real world application.


sounds like a classic In The Pipeline "Things I Won't Work With" [0] tale

[0] example: https://blogs.sciencemag.org/pipeline/archives/2010/02/23/th...


Sounds super easy


In a chemistry lab, it's not so tricky.




Guidelines | FAQ | Lists | API | Security | Legal | Apply to YC | Contact

Search: