Texinfo ultimately gets the @ convention from Brian Reid's Scribe[1], as developed at Carnegie Mellon during the late 70s and commercialized by Unilogic[2,3] in the 80s. Coincidentally, there was a close derivative of Scribe called Mint[4], also developed at Carnegie Mellon in the early 80s for the PERQ (an early personal workstation competing in the category of things like the Sun-1 or Lisp Machines).
Unfortunately, Lout never really took off, but I have fond memories of it. I liked it more than LaTeX, too.
[0]: https://wiki.archlinux.org/title/Lout