In the morning! I second No Agenda! I've been listening for years. Here are some others (non-tech):

- Let's Drink About It: http://www.letsdrinkabout.it/

- The Morning Stream: Geeky morning show, four days a week http://frogpants.com/tms/

- Back to Work: Merlin Mann (Need I say more?) http://5by5.tv/b2w

- Ear Biscuits: An interesting look at YouTubers and "new media" folks. Their stories, etc. https://itunes.apple.com/us/podcast/ear-biscuits/id717407884...

Also, a shameless plug: I've been interviewing developers ranging from Mark Shuttleworth of Canonical to Frederico Knabben of CKEditor. I want to learn from experience. How'd they start their businesses and what knowledge have they accumulated over time? So far, I've racked up 10 interviews. Highlights include:

- Mark Shuttleworth, Canonical

- Mitchell Hashimoto, HashiCorp

- Jeff Haynie, Appcelerator

- John O’Nolan, Ghost

Here's the latest show: http://www.binpress.com/blog/2014/09/09/binpress-podcast-epi...

I like No Agenda too. I just have a hard time finishing their 2.5/3 hour podcasts.

ITM Brother.

+1 For No Agenda. The best podcast in the universe!